Copy PSX Games
You need a piece of specialty software to copy Playstation games.

CloneCD by Slysoft works perfectly.
Step 1: Install CloneCD and open it.
Step 2: Insert the PSX CD, Click the "Read to Image File" and select it as a "Game CD"
Step 3: If you need to change the game from NTSC to PAL, follow our guide here (Although you will have to find a program to convert the image from .ccd to .iso!).
Step 4: Select "Write From Image File" and burn the cd.

Done! You now have a copied PSX CD!